Hmm. ... I've done a large bear and dunked it. If the head will fit in a 5 gallon bucket, tip it to make the Paraloid deeper on one side and put the skull in nose first. Slosh it around a bit to get it up inside. If that doesn't work, up end the skull vertically and pour the paraloid down the nose. It will soak all the inner nasals and run out the other side into whatever you put under it. I did this with a horse and then brushed the paraloid on the outside surfaces. It worked well.
I'm still playing with effects with paraloid. Pouring it into warm water does interesting things too. I haven't the means to spray it. Post a picture of your mold. That should be interesting.
